6.7 chemical capacitance 
　6.8 limit of stability against fluctuations of
　internal variables 
　6.9 le chatelier’s principle 
7 applications of molar gibbs energy diagrams 
　7.1 molar gibbs energy diagrams for binary systems 
　7.2 instability of binary solutions 
　7.3 illustration of the gibbs–duhem relation 
　7.4 two-phase equilibria in binary systems 
　7.5 allotropic phase boundaries 
　7.6 effect of a pressure difference on a two-phase
　equilibrium 
　7.7 driving force for the formation of a new phase 
　7.8 partitionless transformation under local equilibrium 
　7.9 activation energy for a fluctuation 
　7.10 ternary systems 
　7.11 solubility product 
8 phase equilibria and potential phase diagrams 
　8.1 gibbs’ phase rule 
　8.2 fundamental property diagram 
　8.3 topology of potential phase diagrams 
　8.4 potential phase diagrams in binary and multinary systems 
　8.5 sections of potential phase diagrams 
　8.6 binary systems 
　8.7 ternary systems 
　8.8 direction of phase fields in potential phase diagrams 
　8.9 extremum in temperature and pressure 
9 molar phase diagrams 
　9.1 molar axes 
　9.2 sets of conjugate pairs containing molar variables 
　9.3 phase boundaries 
　9.4 sections of molar phase diagrams 
　9.5 schreinemakers’ rule 
　9.6 topology of sectioned molar diagrams 
10 projected and mixed phase diagrams 
　10.1 schreinemakers’ projection of potential phase diagrams 
　10.2 the phase field rule and projected diagrams 
　10.3 relation between molar diagrams and schreinemakers’
　projected diagrams 
　10.4 coincidence of projected surfaces 
　10.5 projection of higher-order invariant equilibria 
　10.6 the phase field rule and mixed diagrams 
　10.7 selection of axes in mixed diagrams 
　10.8 konovalov’s rule 
　10.9 general rule for singular equilibria 
11 direction of phase boundaries 
　11.1 use of distribution coefficient 
　11.2 calculation of allotropic phase boundaries 
　11.3 variation of a chemical potential in a two-phase field 
　11.4 direction of phase boundaries 
　11.5 congruent melting points 
　11.6 vertical phase boundaries 
　11.7 slope of phase boundaries in isothermal sections 
　11.8 the effect of a pressure difference between two phases 
12 sharp and gradual phase transformations 
　12.1 experimental conditions 
　12.2 characterization of phase transformations 
　12.3 microstructural character 
　12.4 phase transformations in alloys 
　12.5 classification of sharp phase transformations 
　12.6 applications of schreinemakers’ projection 
　12.7 scheil’s reaction diagram 
　12.8 gradual phase transformations at fixed composition 
　12.9 phase transformations controlled by a chemical potential 
13 transformations in closed systems 
　13.1 the phase field rule at constant composition 
　13.2 reaction coefficients in sharp transformations
　for p = c +　
　13.3 graphical evaluation of reaction coefficients 
　13.4 reaction coefficients in gradual transformations
　for p = c 
　13.5 driving force for sharp phase transformations 
　13.6 driving force under constant chemical potential 
　13.7 reaction coefficients at constant chemical potential 
　13.8 compositional degeneracies for p = c 
　13.9 effect of two compositional degeneracies for p = c .　
14 partitionless transformations 
　14.1 deviation from local equilibrium 
　14.2 adiabatic phase transformation 
　14.3 quasi-adiabatic phase transformation 
　14.4 partitionless transformations in binary system 
　14.5 partial chemical equilibrium 
　14.6 transformations in steel under quasi-paraequilibrium 
　14.7 transformations in steel under partitioning of alloying elements 
15 limit of stability and critical phenomena 
　15.1 transformations and transitions 
　15.2 order–disorder transitions 
　15.3 miscibility gaps 
　15.4 spinodal decomposition 
　15.5 tri-critical points 
16 interfaces 
　16.1 surface energy and surface stress 
　16.2 phase equilibrium at curved interfaces 
　16.3 phase equilibrium at fluid/fluid interfaces 
　16.4 size stability for spherical inclusions 
　16.5 nucleation 

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